Preheat oven to 350 degrees. Toss potatoes with 3 tablespoons of olive oil and sprinkle with salt. Roast on a rimmed sheet pan for approximately 25-30 minutes or until browned.
in a large skillet, slowly heat the remaining olive oil. Add peppers and onions to the pan and stir in balsamic until caramelized (just a few minutes or longer if you like your veggies a bit more cooked - add more balsamic if cooking longer).
Add cooked peppers and onions to the roasted potatoes, sprinkle with salt and serve.
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